高效液相色谱-电感耦合等离子体质谱联用测定生物样品中无机汞和甲基汞

建立了高效液相色谱(HPLC)和电感耦合等离子体质谱(ICP-MS)联用测定多种生物样品中的无机汞和甲基汞的方法,并对比了提取生物样品中无机汞和甲基汞的不同前处理方法。实验使用5 mol/L的盐酸超声波提取样品中的无机汞和甲基汞。高效液相色谱流动相为含有0.06 mol/L醋酸氨,20μg/L B i,0.1%(V/V)2-巯基乙醇的5%(V/V)甲醇-水溶液,色谱柱为C18反相柱(5μm,3.9 mm×150 mm)。提取液在液相色谱中分离后,进入电感耦合等离子体质谱检测其中无机汞和甲基汞的浓度。测定了人发(GBW 07601),对虾(GBW 08572),鱼肉组织(IAEA MA-B-3/TM)和牛肝(GBW 080193)4种生物标准参考物,结果与标准参考物的标准值相符。无机汞和甲基汞检出限分别为0.3和0.2μg/L。     

抗坏血酸在β-环糊精/二茂铁甲酸修饰电极上的电化学行为及测定

利用主客体化学反应将二茂铁甲酸包络在β-环糊精聚合物的空穴中,用新鲜蛋清作交联剂制成β-环糊精聚合物/二茂铁甲酸化学修饰玻碳电极,用电化学阻抗法和循环伏安法研究了修饰电极的电化学性能。在pH 7.0的磷酸盐缓冲溶液中,该修饰电极对抗坏血酸的电化学氧化有很好的催化活性,氧化峰电流与其浓度在6.2×10-6~5.0×10-3mol/L范围内呈良好的线性关系,线性回归方程为ip=0.4375+0.0301C(ip:μA,C:μmol/L),相关系数r=0.9982,检出限为1.0×10-6mol/L。抗坏血酸和多巴胺在修饰电极上于不同的电位(ΔE=490 mV)被氧化,可用于多巴胺存在下选择性测定抗坏血酸。     

毛细管电泳-柱端安培检测中分离毛细管与检测电极对接方式比较的研究

针对目前毛细管电泳中普遍采用的水平式和直立式两种柱端安培检测形式,在各种可能的对接角度下,以邻苯二酚、间苯二酚和对苯二酚3种二酚作为分离分析测试对象,对分离毛细管与检测电极的对接方式进行了优化比较,并对每一种对接方式的分析特性进行了测试。结果表明：在以3种典型的方式对接时,分离毛细管与检测电极为倒直立式对接时,获得的检测灵敏度最高,响应电流最大,水平式次之,直立式最小。     

臭氧发生器所产生气体中氮氧化物的HPLC法测定

基于氮氧化物溶于水生成HNO2和HNO3的反应,采用NaOH溶液收集氮氧化物,用高效液相色谱法测定氮氧化物,并用分光光度法作对比。结果表明,分光光度法所测结果偏低,高效液相色谱法更准确而且简便、快速,选择性好。     

Existence and uniqueness of traveling waves for non-monotone integral equations with applications

A class of integral equations without monotonicity is investigated. It is shown that there is a spreading speed c^∗>0 for such an integral equation, and that its limiting integral equation admits a unique traveling wave (up to translation) with speed c?c^∗ and no traveling wave with c<c^∗. These results are also applied to some nonlocal reaction-diffusion population models.     

A Schwarz-Pick inequality for harmonic quasiconformal mappings and its applications

The main result of this paper is the sharp generalized Schwarz-Pick inequality for euclidean harmonic quasiconformal mappings with convex ranges, which generalizes a result given by Mateljevi?. As its applications, we obtain the property of quasi-isometry with respect to the Poincaré distance and an analogue of the Koebe theorem for this class of mappings.     

Homeomorphism classification of complex projective complete intersections of dimensions 5, 6 and 7

In this paper we prove that two complete intersections X_n(d){X_n(\underline{d})} and X_n(d￠){X_n(\underline{d}^\prime)} are homeomorphic if and only if they have the same total degree, Pontrjagin classes and Euler characteristics, provided n = 5, 6, 7. This extends earlier result of Fang and Klaus (Manuscr Math 90:139–147, 1996).     

Regularity of the Anosov distributions of Euler-Lagrange deformations of geodesic flows

Let g be a negatively curved Riemannian metric of a closed C ^∞ manifold M of dimension at least three. Let L _λ be a C ^∞ one-parameter convex superlinear Lagrangian on TM such that L₀(v) = \frac12 g(v, v){L_0(v)= \frac{1}{2} g(v, v)} for any v ∈ TM. We denote by j^l{\varphi^\lambda} the restriction of the Euler-Lagrange flow of L _λ on the \frac12{\frac{1}{2}} -energy level. If λ is small enough then the flow j^l{\varphi^\lambda} is Anosov. In this paper we study the geometric consequences of different assumptions about the regularity of the Anosov distributions of j^l{\varphi^\lambda} . For example, in the case that the initial Riemannian metric g is real hyperbolic, we prove that for λ small, j^l{\varphi^\lambda} has C ³ weak stable and weak unstable distributions if and only if j^l{\varphi^\lambda} is C ^∞ orbit equivalent to the geodesic flow of g.     

Transient response of two collinear dielectric cracks in a piezoelectric solid under inplane impacts

The paper is focused on the dynamic analysis of two collinear dielectric cracks in a piezoelectric material under the action of in-plane electromechanical impacts. Considering the dielectric permeability of crack interior, the electric displacements at the crack surfaces are governed by the jumps of electric potential and crack opening displacement across the cracks. The permeable and impermeable crack models are the limiting cases of the general one. The Laplace and Fourier transform techniques are further utilized to solve the mixed initial-boundary-value problem, and then to obtain the singular integral equations with Cauchy kernel, which are solved numerically. Dynamic intensity factors of stress, electric displacement and crack opening displacement are determined in time domain by means of a numerical inversion of the Laplace transform. Numerical results for PZT-5H are calculated to show the effects of the dielectric permeability inside the cracks, applied electric loadings and the geometry of the cracks on the fracture parameters in graphics. The observations reveal that based on the COD intensity factor, a positive electric field enhances the dynamic dielectric crack growth and a negative one impedes the dynamic dielectric crack growth in a piezoelectric solid.     

Well-posedness by perturbations of mixed variational inequalities in Banach spaces

In this paper, we consider an extension of the notion of well-posedness by perturbations, introduced by Zolezzi for a minimization problem, to a mixed variational inequality problem in a Banach space. We establish some metric characterizations of the well-posedness by perturbations. We also show that under suitable conditions, the well-posedness by perturbations of a mixed variational inequality problem is equivalent to the well-posedness by perturbations of a corresponding inclusion problem and a corresponding fixed point problem. Also, we derive some conditions under which the well-posedness by perturbations of a mixed variational inequality is equivalent to the existence and uniqueness of its solution.